Kicking off yet another work week, the stars of “Gossip Girl” were spotted getting down to business on some new episodes today (October 19). Gearing up for a day of shooting, Blake Lively looked bright-eyed and bushy-tailed as she arrived on the Manhattan set. Joining her were Ed Westwick and Leighton Meester who got into character outside the Empire Hotel in the Uptown district of the Big Apple.Tonight at 9pm “Gossip Girl” hits the CW with a brand new episode titled “Enough About Eve.” Per the show’s official Web site: “Vanessa, hoping to finally win her mother Gabriela’s approval, desperately vies with Blair for the honor of delivering the freshman toast at NYU, but at what price? Dan invites Olivia to meet Rufus and Lily, which leads to all sorts of problems for the new couple. Serena and Nate team up to help